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PREPARATION AND CRYSTAL STRUCTURE OF THE TANTALUM BROMIDE CLUSTER COMPLEX [Li(diglyme)2]2[Ta6Br18].

Authors :
Shamshurin, M. V.
Abramov, P. A.
Mikhaylov, M. A.
Sokolov, M. N.
Source :
Journal of Structural Chemistry; Jan2022, Vol. 63 Issue 1, p81-86, 6p
Publication Year :
2022

Abstract

Extracting the reaction product of Ta, Br<subscript>2</subscript>, and LiBr (720 °C, 48 h, mole ratio 1.5:1.75:1.0) with diglyme yields crystals of complex [Li(diglyme)<subscript>2</subscript>]<subscript>2</subscript>[Ta<subscript>6</subscript>Br<subscript>18</subscript>] whose structure is determined by XRD. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00224766
Volume :
63
Issue :
1
Database :
Complementary Index
Journal :
Journal of Structural Chemistry
Publication Type :
Academic Journal
Accession number :
155500724
Full Text :
https://doi.org/10.1134/S0022476622010097