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Reactions of 1-Germatranol Hydrate with Dicarboxylic Acids.
- Source :
- Russian Journal of General Chemistry; Dec2021, Vol. 91 Issue 12, p2430-2440, 11p
- Publication Year :
- 2021
-
Abstract
- The reactions of 1-germatranol hydrate with malonic, succinic, maleic, cork, sebacic acids, and bistrimethylsilyl ester of succinic acid, and also of bis(germatran-1-yl)oxane with succinic acid in acetonitrile, water, methanol, and dimethylsulfoxide were studied. In organic solvents, mono- and dicarboxyl-substituted 1-germatranols are formed, which, like 1-germatranol, are reversibly hydrolyzed with water in an acidic medium. Removing water from reaction mixtures due to evaporation and a topochemical reaction increases the yield of esterified 1-germatranol. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 91
- Issue :
- 12
- Database :
- Complementary Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 154713764
- Full Text :
- https://doi.org/10.1134/S1070363221120112