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Manipulating Matrix Crystallization and Impact Toughness of Polylactide/Elastomer Blends via Tailoring Size and Packing Density of Stereocomplex Crystallites Formed at the Interface.
- Source :
- Macromolecular Materials & Engineering; Jan2022, Vol. 307 Issue 1, p1-9, 9p
- Publication Year :
- 2022
-
Abstract
- Constructing stereocomplex (SC) crystallites at the interface of poly(L‐lactide) (PLLA)/elastomer blends represent a promising strategy to develop heat‐resistant and super‐tough PLLA materials because such SC crystallites can behave as not only nucleator to accelerate crystallization of PLLA matrix but also interfacial binder to strengthen interface. The properties of blends could be largely dominated by the SC interfacial layer, however, it is still unclear how the interfacial structure affects nucleating efficiency and interfacial strength. Herein, taking PLLA/poly(ethylene‐co‐methyl acrylate‐graft‐poly(D‐lactide)) (EMA‐g‐PDLA) blends as an example, EMA‐g‐PDLA bearing different chain lengths and grafting densities is prepared to tailor the size and packing density of interface‐localized SC crystallites. The results indicate that the interfacial structure and properties of the blends have been successfully manipulated. Compared with low‐graft‐density long PDLA chains, high‐graft‐density short ones can readily collaborate with PLLA chains to form numerous SC crystallites with smaller size and higher packing density at the interface and thus dramatically enhance the impact toughness and matrix crystallization rate. Moreover, the toughness is dominated by the content of SC crystallites, but the matrix crystallization is determined by their size and packing density. The work provides a new understanding of SC structure controlling the properties of PLLA/elastomer blends. [ABSTRACT FROM AUTHOR]
- Subjects :
- POLYLACTIC acid
ELASTOMERS
CRYSTALLIZATION
DENSITY
POLYMER blends
Subjects
Details
- Language :
- English
- ISSN :
- 14387492
- Volume :
- 307
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Macromolecular Materials & Engineering
- Publication Type :
- Academic Journal
- Accession number :
- 154690626
- Full Text :
- https://doi.org/10.1002/mame.202100698