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An [FeIII30] molecular metal oxide.
- Source :
- Chemical Communications; 1/4/2022, Vol. 58 Issue 1, p52-55, 4p
- Publication Year :
- 2022
-
Abstract
- Dissolution of FeBr<subscript>3</subscript> in a mixture of acetonitrile and 3,4-lutidine in the presence of an amine results in the formation of an [Fe<subscript>30</subscript>] molecular metal oxide containing alternating layers of tetrahedral and octahedral Fe<superscript>III</superscript> ions. Mass spectrometry suggests the cluster is formed quickly and remains stable in solution, while magnetic measurements and DFT calculations reveal competing antiferromagnetic exchange interactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- ORGANIC conductors
MAGNETIC measurements
MASS spectrometry
ACETONITRILE
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 58
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 154250295
- Full Text :
- https://doi.org/10.1039/d1cc06224g