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Enhanced pressure‐driven force‐electric conversion effect for (Pb,La)(Zr,Ti)O3 ferroelectric ceramics.
- Source :
- Journal of the American Ceramic Society; Feb2022, Vol. 105 Issue 2, p1210-1219, 10p, 1 Color Photograph, 1 Black and White Photograph, 6 Graphs
- Publication Year :
- 2022
-
Abstract
- The pressure‐driven force‐electric conversion materials with extremely rapid response time have been widely used in mining, defense, and energy areas. The discharge process by the force‐electric conversion effect in ferroelectrics is dominated by polar‐nonpolar phase transformation. In this work, (Pb0.985La0.01)(ZrxTi1‐x)O3 (PLZT, x = 0.85–0.94) ceramics is designed by tunning Zr4+/Ti4+ ratio and aliovalent La doping to achieve high remnant polarization (Pr) and excellent temperature stability. We focus on the pressure‐driven depolarization in PLZT ceramics, and their corresponding phase structure, ferroelectric properties, dielectric properties, and thermal depolarization. In PLZT (x = 0.93) ceramics, the original polarization P0 increases to 43.42 μC/cm2. The pressure‐driven depolarization releases 37.66 μC/cm2 with the depolarization proportion of 86.73%, which is attributed to irreversible ferroelectric‐antiferroelectric phase transition. It also exhibits excellent temperature stability up to 120°C (> 36 μC/cm2). This work provides a high‐performance alternative to Pb(Zr0.95Ti0.05)O3 and guidance for the development of pulse power energy conversion devices. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027820
- Volume :
- 105
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Journal of the American Ceramic Society
- Publication Type :
- Academic Journal
- Accession number :
- 153983509
- Full Text :
- https://doi.org/10.1111/jace.18164