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Catalysis of CO2 reduction by diazapyridinophane complexes of Fe, Co, and Ni: CO2 binding triggered by combined frontier MO associations involving a SOMO.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 11/28/2021, Vol. 50 Issue 44, p15983-15995, 13p
- Publication Year :
- 2021
-
Abstract
- Our previous study on the photochemical CO<subscript>2</subscript> reduction into CO catalyzed by the diazapyridinophane complexes of Fe, Co, and Ni revealed that (i) the Co catalyst shows the highest TOF but degrades rapidly, (ii) the Fe catalyst exhibits a lower TOF relative to Co but shows higher robustness, giving a higher TON, and (iii) the Ni complex shows no activity (Sakaguchi et al., Chem. Commun., 2019, 55, 8552). Here we show our DFT results unveiling that the Fe and Co catalysts can utilize multiple sets of frontier MO associations at the CO<subscript>2</subscript> binding by including one of the SOMOs in a high-spin d<superscript>7</superscript> Fe(I) and d<superscript>8</superscript> Co(I) center, respectively, giving an increased driving force for these oxidative addition steps. Remarkably, two-electron reduction of CO<subscript>2</subscript> to CO<subscript>2</subscript><superscript>2−</superscript> at the binding step is driven by the two electrons transferred from different d-based orbitals. The Co<superscript>I</superscript> species binds CO<subscript>2</subscript> at the rate-limiting step with an activation barrier of 15.0 kcal mol<superscript>−1</superscript>, rationalizing the high initial TOF observed. However, the Co<superscript>I</superscript>(CO) species is given as a dead-end product, consistent with its relatively rapid deactivation. The Fe catalyst possesses a slightly higher barrier in CO<subscript>2</subscript> binding (ΔG<superscript>‡</superscript> = 15.8 kcal mol<superscript>−1</superscript>) but does not stabilize the Fe<superscript>I</superscript>(CO) species which readily releases CO (ΔG = 3.5 kcal mol<superscript>−1</superscript>). The Ni catalyst has the smallest barrier in CO<subscript>2</subscript> binding (ΔG<superscript>‡</superscript> = 11.5 kcal mol<superscript>−1</superscript>) but the CO release is largely prohibited by the dead-end Ni<superscript>I</superscript>(CO) species, consistent with its inactive character towards CO<subscript>2</subscript> reduction. The combined results all satisfactorily explain the observed catalytic behaviors. [ABSTRACT FROM AUTHOR]
- Subjects :
- CATALYSTS
CATALYSIS
OXIDATIVE addition
CHARGE exchange
NICKEL catalysts
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 50
- Issue :
- 44
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 153628580
- Full Text :
- https://doi.org/10.1039/d1dt01877a