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Elastic deformability and luminescence of crystals of polyhalogenated platinum(II)–bipyridine complexes.
- Source :
- CrystEngComm; 9/14/2021, Vol. 23 Issue 34, p5891-5898, 8p
- Publication Year :
- 2021
-
Abstract
- Single crystals showing elastic flexibility have attracted increasing attention as next-generation soft materials. Herein, we successfully developed a series of polyhalogenated platinum(II)–bipyridine complexes showing solvent-of-crystallisation-dependent elastic flexibility. Notably, methanol-solvated crystals were the first examples of flexible crystals showing assembly-induced luminescence arising from the triplet metal–metal-to-ligand charge transfer (<superscript>3</superscript>MMLCT) excited state. Furthermore, factors inducing elastic deformability based on the packing structures of the crystals were explored. [ABSTRACT FROM AUTHOR]
- Subjects :
- LUMINESCENCE
PLATINUM
CRYSTALS
SINGLE crystals
CHARGE transfer
Subjects
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 23
- Issue :
- 34
- Database :
- Complementary Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 152225989
- Full Text :
- https://doi.org/10.1039/d1ce00459j