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Synthesis of 1,2-diketones by mercury-catalyzed alkyne oxidation.

Synthesis of 1,2-diketones by mercury-catalyzed alkyne oxidation.

Authors :
Mei, Xiaochuan
Hu, Weican
Gao, Kexin
Gao, Haotian
Wang, Chaoyang
Qian, Guoying
Rong, Zhouting
Source :
Synthetic Communications; 2021, Vol. 51 Issue 17, p2661-2667, 7p, 3 Diagrams, 3 Charts
Publication Year :
2021

Abstract

The first mercury-catalyzed synthesis of 1,2-diketones by alkyne oxidation has been developed. This inexpensive method extends the potential of mercury catalysis and allows the rapid construction of various 1,2-diketones and α-carbonyl amides in good yields with high functional group tolerance. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00397911
Volume :
51
Issue :
17
Database :
Complementary Index
Journal :
Synthetic Communications
Publication Type :
Academic Journal
Accession number :
152058461
Full Text :
https://doi.org/10.1080/00397911.2021.1946082