Aerosol optical properties calculated from size distributions, filter samples and absorption photometer data at Dome C, Antarctica and their relationships between seasonal cycles of sources.

Optical properties of surface aerosols at Dome C, Antarctica in 2007-2013 and their potential source areas are presented. Scattering coefficients (s_sp) were calculated from measured particle number size distributions with a Mie code and from filter samples using mass scattering efficiencies. Absorption coefficients (s_ap) were determined with a 3-wavelength Particle Soot Absorption Photometer (PSAP) and corrected for scattering by using two different algorithms. The scattering coefficients were also compared with s_sp measured with a nephelometer at the South Pole Station (SPO). The minimum s_ap was observed in the austral autumn and the maximum in the austral spring, similar to other Antarctic sites. The darkest aerosol, i.e., the lowest single scattering albedo ?_o ˜ 0.91 was observed in September and October and the highest ?_o ˜ 0.99 in February and March. The uncertainty of the absorption Ångström exponent a_ap is high. The lowest a_ap monthly medians were observed in March and the highest in August – October. The equivalent black carbon (eBC) mass concentrations were compared with eBC measured at three other Antarctic sites: the SPO and two coastal sites, Neumayer and Syowa. The maximum monthly median eBC concentrations are almost the same (~3 ± 1 ng m^-3 ) at all these sites in October-November. This suggests that there is no significant difference in eBC between the coastal and plateau sites. The seasonal cycle of the eBC mass fraction exhibits a minimum f(eBC) ˜ 0.1% in February-March and a maximum ~4-5% in August-October. Source areas were calculated using 50-day FLEXPART footprints. The highest eBC concentrations and the lowest ?_o were associated with air masses coming from South America, Australia and Africa. Vertical simulations that take BC particle removal processes into account show that there would be essentially no BC particles arriving at Dome C from north of latitude 10°S at altitudes < 1600 m. The main biomass-burning regions Africa, Australia and Brazil are more to the south and their smoke plumes have been observed at higher altitudes than that so they can get transported to Antarctica. The seasonal cycle of BC emissions from wildfires and agricultural burning and other fires in South America, Africa and Australia were calculated from data downloaded from the Global Fire Emissions Database (GFED). The maximum total emissions were in August-September but the peak of monthly average eBC concentrations is observed 2 – 3 months later in November not only at Dome C but also at SPO and the coastal stations. The air mass residence-time-weighted BC emissions from South America are approximately an order of magnitude larger than from Africa and Oceania suggesting that South American BC emissions are the largest contributors to eBC at Dome C. At Dome C the maximum and minimum scattering coefficients were observed in austral summer and winter, respectively. At SPO s_sp was similar to that observed at Dome C in the austral summer but there was a large difference in winter, suggesting that in winter SPO is more influenced by sea spray emissions than Dome C. The seasonal cycles of s_sp at Dome C and at the SPO were compared with the seasonal cycles of secondary and primary marine aerosol emissions. The s_sp measured at SPO correlated much better with the sea-spray aerosol emission fluxes in the Southern Ocean than s_sp at Dome C. The seasonal cycles of biogenic secondary aerosols were estimated from monthly average phytoplankton biomass concentrations obtained from the CALIOP satellite sensor data. The analysis suggests that a large fraction of the biogenic scattering aerosol observed at Dome C has been formed in the polar zone but it may take a month for the aerosol to be formed, grown and get transported from the sea level to Dome C. [ABSTRACT FROM AUTHOR]