A Numerical Investigation of the Effects of Fuel Composition on the Minimum Ignition Energy for Homogeneous Biogas-Air Mixtures.

The minimum ignition energy (MIE) requirements for ensuring successful thermal runaway and self-sustained flame propagation have been analysed for forced ignition of homogeneous stoichiometric biogas-air mixtures for a wide range of initial turbulence intensities and CO₂ dilutions using three-dimensional Direct Numerical Simulations under decaying turbulence. The biogas is represented by a CH₄ + CO₂ mixture and a two-step chemical mechanism involving incomplete oxidation of CH₄ to CO and H₂O and an equilibrium between the CO oxidation and the CO₂ dissociation has been used for simulating biogas-air combustion. It has been found that the MIE increases with increasing CO₂ content in the biogas due to the detrimental effect of the CO₂ dilution on the burning and heat release rates. The MIE for ensuring self-sustained flame propagation has been found to be greater than the MIE for ensuring only thermal runaway irrespective of its outcome for large root-mean-square (rms) values of turbulent velocity fluctuation, and the MIE values increase with increasing rms turbulent velocity for both cases. It has been found that the MIE values increase more steeply with increasing rms turbulent velocity beyond a critical turbulence intensity than in the case of smaller turbulence intensities. The variations of the normalised MIE (MIE normalised by the value for the quiescent laminar condition) with normalised turbulence intensity for biogas-air mixtures are found to be qualitatively similar to those obtained for the undiluted mixture. However, the critical turbulence intensity has been found to decrease with increasing CO₂ dilution. It has been found that the normalised MIE for self-sustained flame propagation increases with increasing rms turbulent velocity following a power-law and the power-law exponent has been found not to vary much with the level of CO₂ dilution. This behaviour has been explained using a scaling analysis and flame wrinkling statistics. The stochasticity of the ignition event has been analysed by using different realisations of statistically similar turbulent flow fields for the energy inputs corresponding to the MIE and it has been demonstrated that successful outcomes are obtained in most of the instances, justifying the accuracy of the MIE values identified by this analysis. [ABSTRACT FROM AUTHOR]