TWO Zn(II) AND Co(II) COORDINATION POLYMERS WITH 3-FOLD RIGHT-HANDED HELICAL CHAINS: SYNTHESES, STRUCTURAL CHARACTERIZATION, AND PHOTOLUMINESCENT PROPERTY.

Authors :: Liu, Y.
Li, W.
Yang, Y. -Q.
Chen, M. -S.
Fu, W. -W.
Source :: Journal of Structural Chemistry; May2021, Vol. 62 Issue 5, p740-747, 8p
Publication Year :: 2021
Abstract: Two novel compounds [Zn(bitmb)(L)]·2H<subscript>2</subscript>O and [Co(bitmb)(L)]·2H<subscript>2</subscript>O are prepared under hydrothermal conditions (bitmb = 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene; H<subscript>2</subscript>L = 1,3-bis-(4-carboxy-phenoxy)propane) and characterized by the single crystal X-ray diffraction analysis. Both complexes are isostructural and contain 3-fold right-handed helical 1D chains. IR and PXRD spectra, TG curves, and photoluminescent properties are also studied. [ABSTRACT FROM AUTHOR]

Subjects :: COORDINATION polymers
SINGLE crystals
X-ray diffraction
HYDROGEN bonding
CRYSTAL structure
PROPANE

Full Text Access

Tools