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Electrochemical Dehydrogenative C(sp2)−H Amination.

Authors :
Puthanveedu, Mahesh
Khamraev, Vladislav
Brieger, Lukas
Strohmann, Carsten
Antonchick, Andrey P.
Source :
Chemistry - A European Journal; 5/26/2021, Vol. 27 Issue 30, p8008-8012, 5p
Publication Year :
2021

Abstract

A transition‐metal‐free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
27
Issue :
30
Database :
Complementary Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
150516102
Full Text :
https://doi.org/10.1002/chem.202100960