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Evidence for a lowest energy 3MLCT excited state in [Fe(tpy)(CN)3]−.
- Source :
- Chemical Communications; 5/11/2021, Vol. 57 Issue 38, p4658-4661, 4p
- Publication Year :
- 2021
-
Abstract
- Transient absorption data of [Fe<superscript>II</superscript>(tpy)(CN)<subscript>3</subscript>]<superscript>−</superscript> reveals spectroscopic signatures indicative of <superscript>3</superscript>MLCT with a ∼10 ps kinetic component. These data are supported by DFT and TD-DFT calculations, which show that excited state ordering is responsive to the number of cyanide ligands on the complex. [ABSTRACT FROM AUTHOR]
- Subjects :
- EVIDENCE
LIGANDS (Chemistry)
ABSORPTION
CYANIDES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 38
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 150249885
- Full Text :
- https://doi.org/10.1039/d1cc01090e