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An Efficient Turing‐Type Ag2Se‐CoSe2 Multi‐Interfacial Oxygen‐Evolving Electrocatalyst**.

Authors :
Zhang, Xiao‐Long
Yang, Peng‐Peng
Zheng, Ya‐Rong
Duan, Yu
Hu, Shao‐Jin
Ma, Tao
Gao, Fei‐Yue
Niu, Zhuang‐Zhuang
Wu, Zhi‐Zheng
Qin, Shuai
Chi, Li‐Ping
Yu, Xingxing
Wu, Rui
Gu, Chao
Wang, Cheng‐Ming
Zheng, Xu‐Sheng
Zheng, Xiao
Zhu, Jun‐Fa
Gao, Min‐Rui
Source :
Angewandte Chemie International Edition; Mar2021, Vol. 60 Issue 12, p6553-6560, 8p
Publication Year :
2021

Abstract

Although the Turing structures, or stationary reaction‐diffusion patterns, have received increasing attention in biology and chemistry, making such unusual patterns on inorganic solids is fundamentally challenging. We report a simple cation exchange approach to produce Turing‐type Ag2Se on CoSe2 nanobelts relied on diffusion‐driven instability. The resultant Turing‐type Ag2Se‐CoSe2 material is highly effective to catalyze the oxygen evolution reaction (OER) in alkaline electrolytes with an 84.5 % anodic energy efficiency. Electrochemical measurements show that the intrinsic OER activity correlates linearly with the length of Ag2Se‐CoSe2 interfaces, determining that such Turing‐type interfaces are more active sites for OER. Combing X‐ray absorption and computational simulations, we ascribe the excellent OER performance to the optimized adsorption energies for critical oxygen‐containing intermediates at the unconventional interfaces. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14337851
Volume :
60
Issue :
12
Database :
Complementary Index
Journal :
Angewandte Chemie International Edition
Publication Type :
Academic Journal
Accession number :
149130845
Full Text :
https://doi.org/10.1002/anie.202017016