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Insight into the organocatalytic arylation of azonaphthalenes with α-chloroaldehydes: the general mechanism and origin of selectivities.
- Source :
- Chemical Communications; 1/7/2021, Vol. 57 Issue 2, p219-222, 4p
- Publication Year :
- 2021
-
Abstract
- A systemical computational study was performed to explore the mechanism and origin of selectivities on the organocatalytic arylation of azonaphthalenes with α-chloroaldehydes. The calculated results reveal that the nucleophilicity of active sites and the hydrogen bonds respectively regulate chemo- and stereoselectivities and, for the first time, N-heterocyclic carbene (NHC) can act as a multiple functional base (MFB) catalyst in one system. [ABSTRACT FROM AUTHOR]
- Subjects :
- ARYLATION
ATOMIC hydrogen
HYDROGEN bonding
NUCLEOPHILIC reactions
INSIGHT
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 147965545
- Full Text :
- https://doi.org/10.1039/d0cc07260e