Dielectric and gas adsorption/desorption properties of x-Li(Pc) having one-dimensional channels surrounded by Pc˙− columns.

Authors :: Nishi, Miki
Hoshino, Norihisa
Noro, Shin-ichiro
Fujimoto, Hitoshi
Akutagawa, Tomoyuki
Matsuda, Masaki
Source :: CrystEngComm; 11/28/2020, Vol. 22 Issue 44, p7528-7531, 4p
Publication Year :: 2020
Abstract: A one-dimensional channel system x-Li(Pc), composed of π-radical Pc˙<superscript>−</superscript>, was investigated. Crystal structure analysis revealed that this channel surrounded by Li(Pc) columns is flexible, and gas adsorption/desorption measurements showed selective adsorption/desorption properties. Along with Li<superscript>+</superscript> motion, specific dielectric properties induced by a guest species within the channel were also observed. [ABSTRACT FROM AUTHOR]

Subjects :: GAS absorption & adsorption
DESORPTION
DIELECTRIC properties
DIELECTRICS

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