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Disulfide Promoted C−P Bond Cleavage of Phosphoramide: "P" Surrogates to Synthesize Phosphonates and Phosphinates.
- Source :
- Advanced Synthesis & Catalysis; 11/4/2020, Vol. 362 Issue 21, p4755-4760, 6p
- Publication Year :
- 2020
-
Abstract
- A metal‐free C−P bond cleavage reaction is described herein. Phosphoramides, a phosphine source, can react with alcohols to produce phosphonate and phosphinate derivatives in the presence of a disulfide. P−H2, P‐alkyl, and P,P‐dialkyl phosphoramides can be used as substrates to obtain the corresponding pentavalent phosphine products. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 362
- Issue :
- 21
- Database :
- Complementary Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 146831053
- Full Text :
- https://doi.org/10.1002/adsc.202000511