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Liquid–liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(II) complex.
- Source :
- Chemical Communications; 11/4/2020, Vol. 56 Issue 85, p12989-12992, 4p
- Publication Year :
- 2020
-
Abstract
- Porous molecular crystals (PMCs) should function as new-generation functional porous materials, but the selective crystallisation of PMCs is still difficult. Herein we demonstrate that the liquid–liquid interface between the MeOH/H<subscript>2</subscript>O mixture and alkanes promotes the crystallisation of a Pt(II)-based PMC, rather than the nonporous form. This new crystallisation method allows control of not only the porosity but also the luminescence of the Pt(II) complex crystal. [ABSTRACT FROM AUTHOR]
- Subjects :
- PLATINUM
LIQUID-liquid interfaces
POROUS materials
MOLECULAR crystals
LUMINESCENCE
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 85
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 146650925
- Full Text :
- https://doi.org/10.1039/d0cc04164e