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An efficient bio‐inspired catalytic tool for hydrogen release at room temperature from a stable borohydride solution.

Authors :
Birba, Laura
Ritleng, Vincent
Jierry, Loïc
Agusti, Géraldine
Fongarland, Pascal
Edouard, David
Source :
International Journal of Energy Research; 10/25/2020, Vol. 44 Issue 13, p10612-10627, 16p
Publication Year :
2020

Abstract

Summary: Commercially available open‐cell polyurethane foams (OCPUF) have been successively functionalized with bio‐inspired polydopamine coating (OCPUF@PDA), and activated with cobalt nanoparticles (OCPUF@PDA@Co). The resulting soft structured catalytic support (S2CS) has been used as a highly efficient tool for the release of dihydrogen from a commercially available alkaline sodium borohydride solution at room temperature. With a diluted solution containing 0.4 wt% NaBH4 and 0.4 wt% NaOH, the hydrogen generation rate was of 76.4 ± 3.18 L·h−1·gcat−1 after stabilization of the catalytic activity. The catalytic tool could be used for 10 runs. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
0363907X
Volume :
44
Issue :
13
Database :
Complementary Index
Journal :
International Journal of Energy Research
Publication Type :
Academic Journal
Accession number :
146363112
Full Text :
https://doi.org/10.1002/er.5702