Back to Search
Start Over
C(sp3)–H activation-enabled cross-coupling of two aryl halides: an approach to 9,10-dihydrophenanthrenes.
- Source :
- Chemical Communications; 9/21/2020, Vol. 56 Issue 74, p10942-10945, 4p
- Publication Year :
- 2020
-
Abstract
- A palladium-catalyzed cross-coupling reaction of aryl halides with 2-chlorobenzoic acids has been developed. The reaction forms C(sp<superscript>3</superscript>), C(sp<superscript>2</superscript>)-palladacycles through C(sp<superscript>3</superscript>)–H activation. The palladacycles react with 2-chlorobenzoic acids through two successive C–C cross-couplings, and two C–C bonds are formed with high chemoselectivity. The reaction provides an innovative method for the synthesis of 9,10-dihydrophenanthrenes. [ABSTRACT FROM AUTHOR]
- Subjects :
- ARYL halides
SUZUKI reaction
PALLADACYCLES
CHEMOSELECTIVITY
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 74
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 145956696
- Full Text :
- https://doi.org/10.1039/d0cc04602g