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A soft chemistry approach to the synthesis of single crystalline and highly pure (NH4)CoF3 for optical and magnetic investigations.
- Source :
- Journal of Chemical Physics; 9/14/2020, Vol. 153 Issue 10, p1-8, 8p
- Publication Year :
- 2020
-
Abstract
- A new ionothermal synthesis utilizing 1-alkyl-pyridinium hexafluorophosphates [C<subscript>x</subscript>Py][PF<subscript>6</subscript>] (x = 2, 4, 6) led to the formation of highly crystalline single-phase ammonium cobalt trifluoride, (NH<subscript>4</subscript>)CoF<subscript>3</subscript>. Although ammonium transition-metal fluorides have been extensively studied with respect to their structural and magnetic properties, multiple aspects remain unclear. For that reason, the obtained (NH<subscript>4</subscript>)CoF<subscript>3</subscript> has been investigated over a broad temperature range by means of single-crystal and powder x-ray diffraction as well as magnetization and specific heat measurements. In addition, energy-dispersive x-ray and vibrational spectroscopy as well as thermal analysis measurements were undertaken. (NH<subscript>4</subscript>)CoF<subscript>3</subscript> crystallizes in the cubic perovskite structure and undergoes a structural distortion to a tetragonal phase at 127.7 K, which also is observable in the magnetic susceptibility measurements, which has not been observed before. A second magnetic phase transition occurring at 116.9 K is of second-order character. The bifurcation of the susceptibility curves indicates a canted antiferromagnetic ordering. At 2.5 K, susceptibility measurements point to a third phase change for (NH<subscript>4</subscript>)CoF<subscript>3</subscript>. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 153
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 145734177
- Full Text :
- https://doi.org/10.1063/5.0023343