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Highly Crystalline Ordered Cu-dopedTiO2Nanostructure by Paper Templated Method: Hydrogen Production and Dye Degradation under Natural Sunlight.
- Source :
- Journal of Composites Science; Jun2020, Vol. 4 Issue 2, p1-14, 14p
- Publication Year :
- 2020
-
Abstract
- A highly crystalline ordered Cu-TiO<subscript>2</subscript> nanostructure was synthesized using a simple paper template method using cupric nitrate and titanium isopropoxide as precursors. The structural study by XRD confirmed the formation of highly crystalline anatase phase of Cu-TiO<subscript>2</subscript>. The broad diffraction peaks of Cu-TiO<subscript>2</subscript> exhibit the nanocrystalline nature of the product. The optical study by UV-DRS indicated the red shift in absorption wavelength with an increase in Cu doping, i.e., towards the visible region. The FE-SEM and FE-TEM study validated the formation of spherical shaped nanoparticles of Cu-TiO<subscript>2</subscript> having sizes in the range of 20–30 nm. Considering the absorption in the visible region, the photocatalytic study was performed for water splitting and rhodamine-B (RhB) dye degradation under natural sunlight. The 2% Cu-doped TiO<subscript>2</subscript> showed the highest photocatalytic hydrogen evolution, i.e., 1400 µmol·g<superscript>−1</superscript>·h<superscript>−1</superscript> from water, among the prepared compositions. The photocatalytic performance of Cu-TiO<subscript>2</subscript> conferred complete degradation of RhB dye within 40 min. The higher activity in both cases was attributed to the formation of highly crystalline ordered nanostructure of Cu-doped TiO<subscript>2</subscript>. This synthesis approach has potential to prepare other highly crystalline ordered nanostructured semiconductors for different applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 2504477X
- Volume :
- 4
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Journal of Composites Science
- Publication Type :
- Academic Journal
- Accession number :
- 145502468
- Full Text :
- https://doi.org/10.3390/jcs4020048