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Manganese-catalysed transfer hydrogenation of esters.

Authors :
Oates, Conor L.
Widegren, Magnus B.
Clarke, Matthew L.
Source :
Chemical Communications; 8/7/2020, Vol. 56 Issue 61, p8635-8638, 4p
Publication Year :
2020

Abstract

Manganese catalysed ester reduction using ethanol as a hydrogen transfer agent in place of dihydrogen is reported. High yields can be achieved for a range of substrates using 1 mol% of a Mn(I) catalyst, with an alkoxide promoter. The catalyst is derived from a tridentate P,N,N ligand. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
TRANSFER hydrogenation
ESTERS
CATALYSTS
MANGANESE

Details

Language :
English
ISSN :
13597345
Volume :
56
Issue :
61
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
144871909
Full Text :
https://doi.org/10.1039/d0cc02598d
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