Activation of Peracetic Acid with Lanthanum Cobaltite Perovskite for Sulfamethoxazole Degradation under a Neutral pH: The Contribution of Organic Radicals.

Advanced oxidation processes (AOPs) are effective ways to degrade refractory organic contaminants, relying on the generation of inorganic radicals (e.g., ^•OH and SO₄^•−). Herein, a novel AOP with organic radicals (R-O^•) was reported to degrade contaminants. Lanthanum cobaltite perovskite (LaCoO₃) was used to activate peracetic acid (PAA) for organic radical generation to degrade sulfamethoxazole (SMX). The results show that LaCoO₃ exhibited an excellent performance on PAA activation and SMX degradation at neutral pH, with low cobalt leaching. Meanwhile, LaCoO₃ also showed an excellent reusability during PAA activation. In-depth investigation confirmed CH₃C(O)O^• and CH₃C(O)OO^• as the key reactive species for SMX degradation in LaCoO₃/PAA system. The presence of Cl⁻ (1–100 mM) slightly inhibited the degradation of SMX in the LaCoO₃/PAA system, whereas the addition of HCO₃⁻ (0.1–1 mM) and humic aid (1–10 mg/L) could significantly inhibit SMX degradation. This work highlights the generation of organic radicals via the heterogeneous activation of PAA and thus provides a promising way to destruct contaminants in wastewater treatment. [ABSTRACT FROM AUTHOR]