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Bulk and Surface Properties Regulation of Single/Double Perovskites to Realize Enhanced Oxygen Evolution Reactivity.
- Source :
- ChemSusChem; 6/8/2020, Vol. 13 Issue 11, p3045-3052, 8p
- Publication Year :
- 2020
-
Abstract
- Perovskite‐based oxides have emerged as promising oxygen evolution reaction (OER) electrocatalysts. The performance is closely related to the lattice, electronic, and defect structure of the oxides, which determine surface and bulk properties and consequent catalytic activity and durability. Further, interfacial interactions between phases in a nanocomposite may affect bulk transportation and surface adsorption properties in a similar manner to phase doping except without solubility limits. Herein, we report the development of a single/double perovskite nanohybrid with limited surface self‐reconstruction capability as an OER electrocatalyst. Such superior performance arises from a structure that maintains high crystallinity post OER catalysis, in addition to forming an amorphous layer following the self‐reconstruction of a single perovskite structure during the OER process. In situ X‐ray absorption near edge structure spectroscopy and high‐resolution synchrotron‐based X‐ray diffraction reveal an amorphization process in the hybrid single/double perovskite oxide system that is limited in comparison to single perovskite amorphization, ensuring high catalytic activity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18645631
- Volume :
- 13
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- ChemSusChem
- Publication Type :
- Academic Journal
- Accession number :
- 143652758
- Full Text :
- https://doi.org/10.1002/cssc.202000704