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Synthesis and Sensor Characteristics of Nanoscale Thin Films in the In2O3–SnO2 and Y2O3–TbOx(CeOx) Systems.

Authors :
Arsent'ev, M. Yu.
Kalinina, M. V.
Koval'ko, N. Yu.
Simonenko, T. L.
Morozova, L. V.
Tikhonov, P. A.
Shilova, O. A.
Source :
Inorganic Materials: Applied Research; Mar2020, Vol. 11 Issue 2, p441-447, 7p
Publication Year :
2020

Abstract

(In<subscript>2</subscript>O<subscript>3</subscript>)<subscript>0.95</subscript>(SnO<subscript>2</subscript>)<subscript>0.05</subscript>, (TbO<subscript>х</subscript>)<subscript>0.50</subscript>(Y<subscript>2</subscript>O<subscript>3</subscript>)<subscript>0.50</subscript>, and (CeO<subscript>2</subscript>)<subscript>0.80</subscript>(Y<subscript>2</subscript>O<subscript>3</subscript>)<subscript>0.20</subscript> single-phase cubic solid solution xerogels and nanocrystalline powders have been synthesized via coprecipitation of hydroxides. Using these powders as precursors, nanoscale film electroconductive materials on a corundum substrate have been produced by screen printing. The highest speed of sensor response to ozone is attributed to In<subscript>0.95</subscript>Sn<subscript>0.0</subscript>5O<subscript>1.5</subscript> films, reaching 8–10 s at a temperature of 473 K. (TbO<subscript>х</subscript>)<subscript>0.50</subscript>(Y<subscript>2</subscript>O<subscript>3</subscript>)<subscript>0.50</subscript> thin film is found to be sensitive to changes in the concentrations of (CO + CO<subscript>2</subscript>) (the sensitivity coefficient S = 25.11) and ozone (S = 3.16–7.94). (CeO<subscript>2</subscript>)<subscript>0.80</subscript>(Y<subscript>2</subscript>O<subscript>3</subscript>)<subscript>0.20</subscript> film exhibits a sensor response to (CO + CO<subscript>2</subscript>) (S = 3.10). This study opens up the prospects of using the obtained nanopowders and relevant thin films as materials for resistive gas sensors operating at oxygen pressures of 10<superscript>3</superscript>–10<superscript>4</superscript> Pa. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
20751133
Volume :
11
Issue :
2
Database :
Complementary Index
Journal :
Inorganic Materials: Applied Research
Publication Type :
Academic Journal
Accession number :
142703252
Full Text :
https://doi.org/10.1134/S2075113320020033