Structural and electrochemical characterization of LiMn2O4 and Li1.05Mn1.97Nb0.03O4 with excellent high-temperature cycling stability synthesized by a simple route.

A simple method was applied to control the morphology of LiMn₂O₄ and Li_1.05Mn_1.97Nb_0.03O₄ in the sintering process by premixing a suitable proportion of acetylene black in the raw material. Both specific discharge capacity and cycling stability of the samples were improved. The results demonstrated that the doped samples showed excellent electrochemical performance at both 25 °C and 55 °C. [ABSTRACT FROM AUTHOR]