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Polymer adsorption onto random planar surfaces: Interplay of polymer and surface correlations.

Authors :
Polotsky, Alexey
Schmid, Friederike
Degenhard, Andreas
Source :
Journal of Chemical Physics; 9/8/2004, Vol. 121 Issue 10, p4853-4864, 12p, 1 Diagram, 2 Graphs
Publication Year :
2004

Abstract

We study the adsorption of homogeneous or heterogeneous polymers onto heterogeneous planar surfaces with exponentially decaying site-site correlations, using a variational reference system approach. As a main result, we derive simple equations for the adsorption-desorption transition line. We show that it is preferable to have a small amount of strongly adsorbing sites or monomers rather than a greater amount of weakly adsorbing ones. The results are discussed with respect to their implications for the physics of molecular recognition. © 2004 American Institute of Physics. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00219606
Volume :
121
Issue :
10
Database :
Complementary Index
Journal :
Journal of Chemical Physics
Publication Type :
Academic Journal
Accession number :
14220499
Full Text :
https://doi.org/10.1063/1.1778137