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Selective Synthesis of Z‐Cinnamyl Ethers and Cinnamyl Alcohols through Visible Light‐Promoted Photocatalytic E to Z Isomerization.
- Source :
- Chemistry - An Asian Journal; Mar2020, Vol. 15 Issue 5, p555-559, 5p
- Publication Year :
- 2020
-
Abstract
- A photocatalytic E to Z isomerization of alkenes using an iridium photosensitizer under mild reaction conditions is disclosed. This method provides scalable and efficient access to Z‐cinnamyl ether and allylic alcohol derivatives in high yields with excellent stereoselectivity. Importantly, this method also provides a powerful strategy for the selective synthesis of Z‐magnolol and honokiol derivatives possessing potential biological activity. [ABSTRACT FROM AUTHOR]
- Subjects :
- ETHER synthesis
ISOMERIZATION
ALLYL alcohol
IRIDIUM
STEREOSELECTIVE reactions
Subjects
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 15
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 142060598
- Full Text :
- https://doi.org/10.1002/asia.201901778