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Temperature-responsive dissolution/recrystallization of Zn MOF enables the maximum efficiency and recyclability of catalysts.
- Source :
- Chemical Communications; 2/14/2020, Vol. 56 Issue 13, p1960-1963, 4p
- Publication Year :
- 2020
-
Abstract
- A novel strategy through a temperature-responsive dissolution and recrystallization process has successfully achieved 100% atomic utilization and easy recyclability of heterogeneous metal organic framework dimethylammonium zinc formate (DMZnF) catalysts for highly efficient dehydrogenation of DMF–H<subscript>2</subscript>O for hydrogen generation. DMZnF dissolves as a homogeneous catalyst at high reaction temperatures and then is recrystallized and recycled as a heterogeneous catalyst at low temperatures. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 141728538
- Full Text :
- https://doi.org/10.1039/c9cc09342g