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Preparation and Thermal Decomposition Characteristics of Energetic Metastable Intermodular Composite Si@PVDF/CL-20.
- Source :
- Chinese Journal of Explosives & Propellants; 2019, Vol. 42 Issue 6, p548-556, 9p
- Publication Year :
- 2019
-
Abstract
- In order to improve the energy efficiency of composite nano-metal materials, the energetic intermolecular complexes Si@PVDF/CL-20 with different silicon content (20%, 30% and 40%)were prepared by electrostatic spray method. The heat of combustion of PVDF/CL-20 composites with different ratios was obtained by bomb calorimeter. The morphology of PVDF/CL-20 composite was clarified by using SEM. The effect of Si content on the morphology of Si@PVDF/CL-20 composite particles was also analyzed. The thermal behavior of energetic compounds with different silicon content was studied by DSC-TG, and the kinetic paramters of thermal decomposition were calculated. The thermal analyses indicate that when the PVDF/ CL-20 mass ratio is 1-6, the heat of combustion reaches a maximum value, which can be used as the optimal ratio incoating of nano-Si powder. The SEM results show that when the silicon content is 30%, the composite particles (Si-30% ©PVDF/CL-20) exhibite the best sphericity. The DSC results show that when the silicon content is 20%, a runaway chemical reaction was likely occurred. The effect of Si powder on the decomposition of PVDF/CL-20 composite plays less significant role with the increase of content. The apparent activation energies of Si@PVDF/CL-20 composites calculated by Friedman method are 470. 6, 182.1, 91.7kJ/mol, respectively. The complex decomposition process of Si-20% @PVDF/CL-20 cannot be described by a single kinetic model, whereas those of Si-30% ©PVDF/CL-20 and Si-40% ©PVDF/CL-20 can be well described by a nuclea-tion and growth model. [ABSTRACT FROM AUTHOR]
Details
- Language :
- Chinese
- ISSN :
- 10077812
- Volume :
- 42
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- Chinese Journal of Explosives & Propellants
- Publication Type :
- Academic Journal
- Accession number :
- 141144039
- Full Text :
- https://doi.org/10.14077/j.issn.1007-7812.201903010