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γ-Al2O3 supported/Co-Cr-B catalyst for hydrogen evolution via NH3BH3 hydrolysis.

Authors :
Sait Izgi, Mehmet
Şahin, Ömer
Saka, Cafer
Source :
Materials & Manufacturing Processes; 2019, Vol. 34 Issue 14, p1620-1626, 7p
Publication Year :
2019

Abstract

This assay investigates the Co-Cr-B catalyst effect supported on γ-Al<subscript>2</subscript>O<subscript>3</subscript> to produce hydrogen (HG) from ammonia-borane hydrolysis (ABH). For characterization of this catalyst, SEM-EDX, XRD, FTIR and BET surface area analysis were performed. The maximum hydrogen generation rate (HGR) with this catalyst used for the ABH was 3260 ml min<superscript>−1</superscript> g<superscript>−1</superscript><subscript>catalyst</subscript>. The recyclability tests for the Co-Cr-B/γ-AlO<subscript>3</subscript> catalyst on the ABH have maintained an activity of 68% even after four hydrolysis treatments. Also, the activation energy (Ea) obtained using the Co-Cr-B catalyst supported on γ-AlO<subscript>3</subscript> for the ABH was 56.06 kJ/mol. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
10426914
Volume :
34
Issue :
14
Database :
Complementary Index
Journal :
Materials & Manufacturing Processes
Publication Type :
Academic Journal
Accession number :
139861534
Full Text :
https://doi.org/10.1080/10426914.2019.1594280