Large flexoelectric response in PMN-PT ceramics through composition design.

Flexoelectricity yields electric polarization through graded strains and exists in various kinds of solid dielectrics but usually with a weak coupling response. In this letter, several Bi-doped Pb(Mg_2/3Nb_1/3)O₃-xPbTiO₃ (PMN-xPT) ferroelectric ceramics were prepared and the interplay of their piezoelectricity and flexoelectricity was systematically investigated. The largest flexoelectric response (∼300 μC/m) was 30 times larger than that of pure PMN-PT and was observed in the Bi-doped PMN-32PT, where the after poling piezoelectric coefficients were also the largest (990 pC/N) among all the compositions. This suggests that the apparent flexoelectricity in ferroelectrics is highly related to the bulk piezoelectricity. Therefore, introducing a local structural heterogeneity is considered as a feasible approach to achieve an ultrahigh piezoelectric response while also providing an ultrahigh flexoelectricity. [ABSTRACT FROM AUTHOR]