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Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water.
- Source :
- Chemical Communications; 10/7/2019, Vol. 55 Issue 78, p11735-11738, 4p
- Publication Year :
- 2019
-
Abstract
- The first two inorganic–organic hybrid three-dimensional (3D) polyoxotantalates (POTas) and the first two inorganic–organic hybrid 2D POTas have been obtained. All of these high-dimensional POTas are built from a new-type POTa dimeric cluster {Cu(en)(Ta<subscript>6</subscript>O<subscript>19</subscript>)}<subscript>2</subscript>/{Cu(enMe)(Ta<subscript>6</subscript>O<subscript>19</subscript>)}<subscript>2</subscript> (en = ethylenediamine, enMe = 1,2-diaminopropane) bridged by copper complexes. Interestingly, extended POTas 1 and 3 can undergo single-crystal to single-crystal structural transformations triggered by water. [ABSTRACT FROM AUTHOR]
- Subjects :
- WATER
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 78
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 138830102
- Full Text :
- https://doi.org/10.1039/c9cc05884b