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Development of a new Lindqvist-like Fe6 cluster secondary building unit for MOFs.
- Source :
- Chemical Communications; 9/16/2019, Vol. 55 Issue 72, p10729-10732, 4p
- Publication Year :
- 2019
-
Abstract
- This work demonstrates a new Lindqvist-like [Fe <superscript>III</superscript><subscript>6</subscript> (μ<subscript>6</subscript>-O)L<subscript>4</subscript>Cl<subscript>6</subscript>]<superscript>2−</superscript> (Fe<subscript>6</subscript>, L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol) cluster for the construction of a novel class of Fe-cluster organic frameworks. The novel Fe<subscript>6</subscript> cluster can be used to build not only a homometallic MOF, but also a heterometallic MOF by introducing copper halide clusters to the reaction system. In particular, the heterometallic MOF achieved a skillful combination of Fe<subscript>6</subscript> SBU and cuprous–halide clusters for the first time. Our synthesis strategy opens up an effective avenue to novel Fe-cluster-based MOF materials. [ABSTRACT FROM AUTHOR]
- Subjects :
- COPPER clusters
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 72
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 138442801
- Full Text :
- https://doi.org/10.1039/c9cc04999a