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A Very Strong Methylation Agent: [Me2Cl][Al(OTeF5)4].
- Source :
- Angewandte Chemie International Edition; 7/15/2019, Vol. 58 Issue 29, p9807-9810, 4p
- Publication Year :
- 2019
-
Abstract
- A new chloronium‐containing salt, [Me2Cl][Al(OTeF5)4], was synthesized on multigram scale by means of a simple one‐pot procedure. The isolated product can be handled at room temperature and used as a strong electrophilic methylation agent. This is demonstrated by the methylation of the very weak bases P(CF3)3, PF3, MeI, and MeBr. [ABSTRACT FROM AUTHOR]
- Subjects :
- METHYLATION
LEWIS acids
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 58
- Issue :
- 29
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 137720469
- Full Text :
- https://doi.org/10.1002/anie.201904007