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Transition-metal- and oxidant-free directed anodic C–H sulfonylation of N,N-disubstituted anilines with sulfinates.
- Source :
- Chemical Communications; 8/7/2019, Vol. 55 Issue 61, p8995-8998, 4p
- Publication Year :
- 2019
-
Abstract
- A new, practical directed anodic C–H sulfonylation of N,N-disubstituted anilines with sodium sulfinates for producing o- or p-amino arylsulfones and diarylsulfones is described. Employing the anodic strategy, the reaction proceeds efficiently under mild (room temperature) and transition-metal- and chemical oxidant-free conditions, and enables the formation of C–S bonds via directed activation of ortho- or para-C–H bond to the amino group with broad substrate scope and excellent site selectivity. [ABSTRACT FROM AUTHOR]
- Subjects :
- ANILINE
AMINO group
SULFINATES
ANODIC oxidation of metals
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 61
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 137703507
- Full Text :
- https://doi.org/10.1039/c9cc03789f