In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm).

Authors :: Alexandru, Maria-Gabriela
Visinescu, Diana
Braun-Cula, Beatrice
Shova, Sergiu
Lloret, Francesc
Julve, Miguel
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 6/14/2019, Vol. 48 Issue 22, p7532-7536, 5p
Publication Year :: 2019
Abstract: Two new examples of cyanido-bridged {Fe<superscript>III</superscript>Ln<superscript>III</superscript>}<subscript>2</subscript> molecular squares, with pyim and PPh<subscript>3</subscript>O as capping ligands at the Ln<superscript>III</superscript> sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H-imidazol-2-yl)pyridine, PPh<subscript>3</subscript>PO = triphenylphosphine oxide]. [ABSTRACT FROM AUTHOR]

Subjects :: SQUARE
RARE earth metals
REPRODUCTION
LIGANDS (Chemistry)
OXIDES

Language :: English
ISSN :: 14779226
Volume :: 48
Issue :: 22
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 136816636
Full Text :: https://doi.org/10.1039/c9dt01445d

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