Liquid-liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors.

Information on liquid-liquid phase separation (LLPS) and viscosity (or diffusion) within secondary organic aerosol (SOA) is needed to improve predictions of particle size, mass, reactivity, and cloud nucleating properties in the atmosphere. Here we report on LLPS and viscosities within SOA generated by the photooxidation of diesel fuel vapors. Diesel fuel contains a wide range of volatile organic compounds, and SOA generated by the photooxidation of diesel fuel vapors may be a good proxy for SOA from anthropogenic emissions. In our experiments, LLPS occurred over the relative humidity (RH) range of ~70% to ~100%, resulting in an organic-rich outer phase and a water-rich inner phase. These results may have implications for predicting the cloud nucleating properties of anthropogenic SOA since the organic-rich outer phase can lower the kinetic barrier for activation to a cloud droplet. At ≤10% RH, the viscosity was in the range of ≥1×10⁸Pas, which corresponds to roughly the viscosity of tar pitch. At 38-50% RH the viscosity was in the range of 1×10⁸-3×10⁵Pas. These measured viscosities are consistent with predictions based on oxygen to carbon elemental ratio (O:C) and molar mass as well as predictions based on the number of carbon, hydrogen, and oxygen atoms. Based on the measured viscosities and the Stokes-Einstein relation, at ≤10% RH diffusion coefficients of organics within diesel fuel SOA is ≤5.4×10^-17cm²s^-1 and the mixing time of organics within 200nm diesel fuel SOA particles (τ_mixing) is ⪆50h. These small diffusion coefficients and large mixing times may be important in laboratory experiments, where SOA is often generated and studied using low RH conditions and on time scales of minutes to hours. At 38-50% RH, the calculated organic diffusion coefficients are in the range of 5.4×10^-17 to 1.8×10^-13cm²s^-1 and calculated τ_mixing values are in the range of ~0.01h to ~50h. These values provide important constraints for the physicochemical properties of anthropogenic SOA. [ABSTRACT FROM AUTHOR]