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Cu(I)/Ionic Liquids Promote the Conversion of Carbon Dioxide into Oxazolidinones at Room Temperature.
- Source :
- Molecules; Apr2019, Vol. 24 Issue 7, p1241-1241, 1p, 1 Diagram, 3 Charts, 4 Graphs
- Publication Year :
- 2019
-
Abstract
- Recently, the efficient chemical fixation of carbon dioxide (CO<subscript>2</subscript>) into high value chemicals without using noble metal catalysts has become extremely appealing from the viewpoint of sustainable chemistry. In this work, a one-pot three component reaction of propargylic alcohols, anines and CO<subscript>2</subscript> that can proceed in an atom economy and environmentally benign manner by combination of CuI and tetrabutylphosphonium imidazol ([P<subscript>4444</subscript>][Im]) as a catalyst was described. Catalysis studies indicate that this catalytic system is an effective catalyst for the conversion of CO<subscript>2</subscript> into oxazolidinones at room temperature and ambient pressure without any solvent. The results provide a useful way to design novel noble metal-free catalyst systems for the transformation of CO<subscript>2</subscript> into other valuable compounds. [ABSTRACT FROM AUTHOR]
- Subjects :
- CHEMICAL reactions
CARBON dioxide
NANOPARTICLES
CATALYSIS
IONIC liquids
Subjects
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 24
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- 135866240
- Full Text :
- https://doi.org/10.3390/molecules24071241