Property Improvement of GaAs Surface by 1-Octadecanethiol Passivation.

In this study the effects of 1-Octadecanethiol (ODT, 1-CH₃ [CH₂]₁₇SH) passivation on GaAs (100) surface and GaAs/Al₂O₃ MOS capacitors are investigated. The results measured by X-ray photoelectric spectroscopy (XPS), Raman spectroscopy and scan electron microscopy (SEM) show that the ODT passivation can obviously suppress the formation of As-O bonds and Ga-O bonds on the GaAs surface and produce good surface morphology at the same time, and especially provide better protection against environmental degradation for at least 24 h. The passivation time is optimized by photoluminescence (PL), and the maximum enhancement of PL intensity was 116%. Finally, electrical property of a lower leakage current was measured using the metal-oxide-semiconductor capacitor (MOSCAP) method. The results confirm the effectiveness of ODT passivation on GaAs (100) surface. [ABSTRACT FROM AUTHOR]