Extrinsic Heavy Metal Atom Effect on the Solid‐State Room Temperature Phosphorescence of Cyclic Triimidazole.

Four coordination compounds [Zn3(CH3COO)6(H2O)2](TT)2 [Cd(H2O)6](ClO4)2(TT)2, [Cd(H2O)6](BF4)2(TT)2, [Zn(H2O)6](BF4)2(TT)2 (1–4) accommodating the crystallization induced emissive triimidazo[1,2‐a:1′,2′‐c:1′′,2′′‐e][1,3,5]triazine (TT) as a guest in their crystal lattice are isolated and fully photophysically and structurally characterized. Their emission properties are compared with those of afterglow TT and interpreted taking into account the heavy atom effect and crystal packing similarities and differences. In the case of 1, due to the closeness of the TT H‐aggregates arrangement with that of the phosphor's pure phase, the observed intensification of the phosphorescent emission at the expense of the prompt one is attributed to the extrinsic heavy atom effect of Zn. In 2 and 3, the heavier Cd atom is responsible for a decrease in the lifetimes of the afterglow emission, despite the presence of tightly overlapped H‐dimers in the crystal structure. Finally, for 4, isostructural with 3, the Zn atom reveals in RTUP lifetime comparable with that of 1. Solid‐state emission properties of four discrete Zn and Cd coordination compounds accommodating cyclic triimidazole as a guest are investigated. The intriguing photophysics of the organic phosphor is preserved and differently affected by the metal thanks to the presence of H‐aggregates in the crystal structures. [ABSTRACT FROM AUTHOR]