Superhydrophobic Coatings from Beeswax‐in‐Water Emulsions with Latent Heat Storage Capability.

Beeswax particles are homogenously emulsified in commercial aqueous polymer dispersion, without additional dispersing agents and surfactants. Emulsions display very good stability with wax droplet size distribution around 350 nm. The wax to polymer ratio in the emulsions can be tuned without compromising emulsion stability. The emulsions are spray coated in order to create either hydrophobic or superhydrophobic coatings. For superhydrophobicity, silica nanoparticles are dispersed in the emulsions at different concentrations. Beeswax‐rich coatings such as the ones with 1:1 beeswax:polymer ratio or more, including the superhydrophobic ones, demonstrate promising latent heat storage characteristics, suitable for thermal management applications. Electron microscopy studies show that as a result of emulsification, the polymer encapsulates the wax droplets/particles as a nanothin shell, preventing a major problem related to low melting point phase change materials referred to as leaching. Hence, the coatings can be heated well above the melting point of beeswax (≈62 °C) and can still demonstrate effective heat storage during the cooling stage. This water‐based coating process using ecofriendly material constituents can easily be scaled up and used in responsive coating applications, ranging from electronics to interior or exterior structural buildings requiring efficient energy management and thermal energy savings. Heat storing superhydrophobic nanocomposite coatings are developed by following a totally green process, only water as solvent, and using beeswax as the phase change material. Beeswax is homogenized with an environmentally approved waterborne acrylic dispersion forming very stable microemulsions (≈300 nm). Silica nanoparticle suspended emulsions are applied as superhydrophobic heat storage coatings. [ABSTRACT FROM AUTHOR]