Hafnium Diboride as a saturable absorber for Q-switched lasers.

Hafnium diboride (HfB₂) is used in hypervelocity re-entry vehicles (such as intercontinental ballistic missile (ICBM) or ICBM heat shields), nuclear reactors and aerodynamic leading edges because of its strong tensile strength and high thermal resistance. HfB₂ is an ultra-high-temperature ceramic (UHTC) with a melting point of 3250°C. In this paper, we study the performance of HfB₂ as a saturable absorber in Q-switched lasers. HfB₂ has a non-saturable absorptance of 2.5 dB/µm, a saturable absorptance of 0.8 dB/µm and a saturation fluence of 12 µJ/cm². In addition, the saturation lifetime is estimated as 989.3 ps, while the recovery lifetimes are estimated as 254.9 and 22.1 ps. As a saturable absorber in our Q-switched laser, we observed pulses with durations between 880 and 2000 ns. With the addition of an acousto-optic modulator, we have observed Q-switching mode-locking, with pulses as low as 250 ns. HfB₂ can potentially work at very high power, since its damage fluence is no less than 361 mJ/cm². [ABSTRACT FROM AUTHOR]