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Cover Picture: On the Design of Radical–Radical Cocrystals (Angew. Chem. Int. Ed. 5/2019).

Authors :
Nascimento, Mitchell A.
Heyer, Elodie
Clarke, Joshua J.
Cowley, Hugh J.
Alberola, Antonio
Stephaniuk, Nadia
Rawson, Jeremy M.
Source :
Angewandte Chemie International Edition; 1/28/2019, Vol. 58 Issue 5, p1221-1221, 1p
Publication Year :
2019

Abstract

SOMO Wrestling Molecules of C6F5CNSSN and TEMPO radicals tangle on the Dohyō. In their Communication on page 1371, J. M. Rawson and co‐workers implement favorable electrostatic contacts to drive cocrystal formation between different radicals. The concept is exemplified through the preparation and structural characterization of three sets of radical cocrystals: the 2:2 cocrystal [PhCNSSN]2[MBDTA]2 and the 2:1 cocrystals [C6F5CNEEN]2[TEMPO] (E=S, Se). [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14337851
Volume :
58
Issue :
5
Database :
Complementary Index
Journal :
Angewandte Chemie International Edition
Publication Type :
Academic Journal
Accession number :
134216850
Full Text :
https://doi.org/10.1002/anie.201814226