Removal of Arsenic(III) from Aqueous Solution Using Metal Organic Framework-Graphene Oxide Nanocomposite.

MIL-53(Al)-graphene oxide (GO) nanocomposites of different GO to MIL-53(Al) mass ratios (1% to 25% GO) were synthesized and tested for removal of arsenite (As(III)), which is a well-known groundwater contaminant. The properties of MIL-53(Al)-GO nanocomposites were characterized using X-ray Diffraction (XRD), Fourier Transform Infrared (FT-IR) Spectroscopy, Brunauer-Emmett-Teller (BET) surface area measurements, and Scanning Electron Microscopy (SEM). Batch experiments were performed on MIL-53(Al)-GO nanocomposites for As(III) adsorption in aqueous solutions to investigate adsorption kinetics and isotherm behavior under varying environmental conditions. The effects of solution pH (2 to 11), initial As(III) concentrations (10–110 mg/L), adsorbent dosage (0.2–3.0 g/L), and temperature (298–318 K) on As(III) adsorption were investigated. MIL-53(Al)-GO nanocomposites showed higher adsorption of As(III) than pristine MIL-53(Al) and GO individually. As (III) removal was optimized at a ratio of 3% GO in the MIL-53(Al)-GO nanocomposite, with an adsorption capacity of 65 mg/g. The adsorption kinetics and isotherms followed pseudo-second-order and Langmuir isotherm models, respectively. Overall, these results suggest that MIL-53(Al)-GO nanocomposite holds a significant promise for use in the remediation of As (III) from groundwater and other aqueous solutions. [ABSTRACT FROM AUTHOR]