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Triphenyl(3,4,5-triiodophenyl)-methane.

Authors :
Reddy, C. Malla
Nangia, Ashwini
Jetti, Ram K.R.
Boese, Roland
Source :
Acta Crystallographica: Section C (Wiley-Blackwell); May2004, Vol. 60 Issue 5, po331-o333, 3p, 4 Diagrams, 2 Charts
Publication Year :
2004

Abstract

The crystal structure of the title compound, alternatively called 1,2,3-triiodo-5-(triphenylmethyl)benzene, C<subscript>25</subscript>H<subscript>17</subscript>I<subscript>3</subscript>, is analysed in terms of I···I and I···π interactions and the herring-bone T motif between phenyl groups. There are two molecules in the asymmetric unit, denoted A and B. Inversionrelated A molecules are connected via an I···π interaction (3.641 Å, to a C-C bond mid-point) to form an I···π dimer, and these dimers are connected through symmetry-independent B molecules via I···I [3.5571 (15) Å] and I···π (3.561 Å, to a C-C bond mid-point) interactions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
60
Issue :
5
Database :
Complementary Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
13401373
Full Text :
https://doi.org/10.1107/S0108270104006146