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Isolation of reactive Ln(ii) complexes with C5H4Me ligands (CpMe) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-CpMe)K(18-crown-6)][CpMe3LnII] (Ln = Tb, Ho)
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 12/28/2018, Vol. 47 Issue 48, p17285-17290, 6p
- Publication Year :
- 2018
-
Abstract
- Although attempts to make the Y(ii) complex, (Cp<superscript>Me</superscript><subscript>3</subscript>Y)<superscript>1−</superscript> (Cp<superscript>Me</superscript> = C<subscript>5</subscript>H<subscript>4</subscript>Me), by reduction of Cp<superscript>Me</superscript><subscript>3</subscript>Y with potassium were unsuccessful and the products of potassium reduction of Cp<superscript>Me</superscript><subscript>3</subscript>Ln for Ln = La and Pr led to ring-opening reduction of THF, we report that crystallographically-characterizable Ln(ii) complexes of Tb and Ho can be isolated by reducing Cp<superscript>Me</superscript><subscript>3</subscript>Ln(THF) with KC<subscript>8</subscript> in THF in the presence of 18-crown-6 (18-c-6). X-ray crystallography revealed that these complexes are isolated with a methylcyclopentadienide inverse sandwich countercation: [(18-c-6)K(μ-Cp<superscript>Me</superscript>)K(18-c-6)][Cp<superscript>Me</superscript><subscript>3</subscript>Ln] (Ln = Tb, Ho). Although reduction of Cp<superscript>Me</superscript><subscript>3</subscript>Ln with potassium in the presence of the 2.2.2-cryptand (crypt) chelate has not generally provided fully-characterizable, crystalline products, in the case of Dy, crystals of [K(crypt)][Cp<superscript>Me</superscript><subscript>3</subscript>Dy] could be isolated. [ABSTRACT FROM AUTHOR]
- Subjects :
- LIGANDS (Chemistry)
POTASSIUM
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 47
- Issue :
- 48
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 133505221
- Full Text :
- https://doi.org/10.1039/c8dt03890b