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Retro-metal-ene versus retro-Aldol: mechanistic insight into Rh-catalysed formal [3+2] cycloaddition.
- Source :
- Chemical Communications; 12/14/2018, Vol. 54 Issue 96, p13551-13554, 4p
- Publication Year :
- 2018
-
Abstract
- Theoretical calculations have been performed to investigate the mechanism and stereoselectivity of rhodium-catalysed intramolecular [3+2] cycloaddition for construction of a substituted hexahydropentalene complex. A new C–C bond cleavage mechanism, retro-Aldol-type, is proposed and verified for this Rh-catalysed [3+2] cycloaddition reaction. [ABSTRACT FROM AUTHOR]
- Subjects :
- CYCLOPENTADIENE
RING formation (Chemistry)
RHODIUM catalysts
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 96
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 133278092
- Full Text :
- https://doi.org/10.1039/c8cc08335e