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Immobilization of a Full Photosystem in the Large‐Pore MIL‐101 Metal–Organic Framework for CO2 reduction.
- Source :
- ChemSusChem; 9/21/2018, Vol. 11 Issue 18, p3315-3322, 8p
- Publication Year :
- 2018
-
Abstract
- Abstract: A molecular catalyst [Cp*Rh(4,4′‐bpydc)]<superscript>2+</superscript> and a molecular photosensitizer [Ru(bpy)<subscript>2</subscript>(4,4′‐bpydc)]<superscript>2+</superscript> (bpydc=bipyridinedicarboxylic acid) were co‐immobilized into the highly porous metal–organic framework MIL‐101‐NH<subscript>2</subscript>(Al) upon easy postsynthetic impregnation. The Rh–Ru@MIL‐101‐NH<subscript>2</subscript> composite allows the reduction of CO<subscript>2</subscript> under visible light, while exhibiting remarkable selectivity with the exclusive production of formate. This Rh–Ru@MIL‐101‐NH<subscript>2</subscript> solid represents the first example of MOFs functionalized with both a catalyst and a photosensitizer in a noncovalent fashion. Thanks to the coconfinement of the catalyst and photosensitizer into the cavity's nanospace, the MOF pores are used as nanoreactors and enable molecular catalysis in a heterogeneous manner. [ABSTRACT FROM AUTHOR]
- Subjects :
- PHOTOSYSTEMS
PHOTOSENSITIZERS
POROUS metals
POROUS materials
THERMOGRAVIMETRY
Subjects
Details
- Language :
- English
- ISSN :
- 18645631
- Volume :
- 11
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- ChemSusChem
- Publication Type :
- Academic Journal
- Accession number :
- 131908526
- Full Text :
- https://doi.org/10.1002/cssc.201801066